Product ID:CARBURTR TUNEUP, 00008700
MSDS Date:05/14/1990
FSC:6850
NIIN:00N038657
MSDS Number: BRHJN

VALVOLINE INC

LEXINGTON, KY 40512
US

Emergency Phone: 606-274-5263

Info Phone: 606-264-7000

Cage: GO029

VALVOLINE OIL CO

14000 LEXINGTON, KY 40512 US

Telephone: 606-357-7206 / 800-274-5263

Cage: 72527

PROPER AUTH AS REQ, THAT A SPILL HAS OCCURED.

RTECS: 9999999ZZ

UNDER SPECIFIED CNDTNS. ENGINEERING OR

RTECS: 9999999ZZ

BEEN SUGGESTED AS CAUSE OF FOLLOWING EFTS

RTECS: 9999999ZZ

(CAS # 108-88-3) APPEARS ON THE NAVY LISTING OF

RTECS: 9999999ZZ

APPROPRIATE HEALTH PROFESSIONALS CONCERNING THE

RTECS: 9999999ZZ

PROPANE

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 25-30%

OSHA PEL 1000 PPM

ACGIH TLV: SIMPLE ASPHYXIANT

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 30-35%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANOL;(METHYL ALCOHOL)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 20-25%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETONE (SARA III)

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 10-15%

OSHA PEL 1000PPM

ACGIH TLV: 750PPM/1000STEL;9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

DIACETONE ALCOHOL (4-HYDROXY-4-METHYL-2-PENTANONE)

CAS: 123-42-2

RTECS: SA9100000

Fraction By Weight: 1-5%

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM

GROUNDED AND/OR BONDED WHEN MATERIAL IS

RTECS: 9999999ZZ

CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT

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TO SALVAGE TANK. REMAINING LIQ MAY BE TAKEN UP ON

RTECS: 9999999ZZ

& SHOVELED INTO CNTNRS. PVNT RUN-OFF TO

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:MAY CAUSE SEVERE IRRIT,
REDNESS, TEARING, BLURRED VISION. SKIN:PRLNGD/RPTD CNTCT MAY CAUSE
MOD IRRIT, DEFAT, DERM. INHAL:EXCESS INHAL OF VAPS MAY CAUSE NASAL
& RESP IRRIT, CNS EFTS INCLUDING DIZZINESS, WEAKNESS, FATIGUE,
NAUS, HEADACHE, & POSSIBLE UNCONSCIOUSNESS & EVEN ASPHYXIATION.
INGEST:(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:MAY CAUSE GI IRRIT, NAUS, VOMIT, &
DIARR. ASPIR OF MATL INTO LUNGS MAY CAUSE CHEM PNEUMONIA WHICH MAY
BE FATAL. CHRONIC:OVEREXP HAS APPARENTLY BEEN FOUND TO CAUSE THE
FOLLOWING EFTS IN LAB AN IMALS:LIVER ABNORM, KIDNEY DMG,
ANEMIA,LUNG DMG, EYE DMG, BRAIN DMG, SPLEEN DMG, NERV SYS DMG.
OVEREXP HAS (ING 12)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN:THORO WASH W/SOAP & WATER. EYE:FLUSH WITH LARGE AMOUNTS
OF WATER, LIFTING UPPER & LOWER LIDS OCCASIONALLY, GET MD.
INGEST:DO NOT INDUCE VOMITING, KEEP PERSON WARM, QUIET & GET MD.
ASPIRATION OF M ATERIAL INTO LUNGS DUE TO VOMIT CAN CAUSE CHEM
PNEUMONIA WHICH MAY BE FATAL. INHAL:MOVE TO FRESH AIR. IF BRTHG IS
DFCLT, GIVE O*2. IF BRTHG HAS STOPPED, GIVE ARTF RESP. KEEP PERS
WARM, QUIET & GET MD.

Flash Point Method:TCC
Flash Point:-4F,-20C
Lower Limits:1.2%
Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MATL IS HIGHLY VOLATILE & READILY GIVES
OFF VAPS WHICH MAY TRAVEL ALONG GROUND OR BE MOVED BY VENT, &
IGNITED BY PILOT LIGHTS, OTHER FLAMES, SPARKS, (SUPDAT)

Spill Release Procedures:SMALL SPILL:ABSORB LIQ ON PAPER, VERMICULITE,
FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. LRG SPILL:ELIM ALL
IGNIT SOURCES (FLARES, FLAMES INCL PILOT LIGHT, ELEC SPARKS). PERS
NOT WEARING PROT EQUIP SHOULD BE EXCLUDED FROM SPILL AREA UNTIL
(ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT
RESIDUES (VAP, LIQ, &/OR SOLID).
Other Precautions:ALL HAZARD PRECAUTIONS GIVEN SHOULD BE OBSERVED.

Respiratory Protection:ALL RESPS MUST BE NIOSH/MSHA APPROVED. IF
WORKPLACE EXPOS LIMIT(S) OF PROD OR ANY COMPONENT IS EXCEEDED AN
AIR SUPPLIED RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CNTRL.
OSHA REGS ALSO PERMIT OTHER RESPS (NEGATIVE PRESS TYPE) (ING 11)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NOT REQUIRED UNDER NORMAL CONDITIONS OF USE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:HEATERS, SMKNG, ELEC MOTORS, STATIC DISCHARGE, OR OTHER IGNIT
SOURCES AT LOCATIONS DISTANT FROM MATL HANDLING PT. NEVER USE
WELDING/CUTTING TORCH NEAR DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JU
ST RESIDUE) CAN IGNITE EXPLO. ALL FIVE GALLON PAILS & LARGER METAL
CNTNRS INCL TANK CARS/TRUCKS SHOULD BE (ING 6)

Boiling Pt:B.P. Text:133F,56C
Vapor Pres:181.7 @68F
Vapor Density:HVR/AIR
Spec Gravity:0.840 @ 68F
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:CLEAR COLORLESS LIQUID
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, OPEN FLAME, AND PROLONGED
STORAGE AT ELEVATED TEMPERATURES.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:SMALL AND LARGE SPILLS:DISPOSE OF IN ACCORDANCE
WITH LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.